Zur Seitenansicht
 

Titelaufnahme

Titel
Light-triggered radical silane-ene chemistry using a monoalkyl substituted bis(trimethylsilyl)silane
Verfasser / Verfasserin Steindl, Johannes ; Svirkova, Anastasiya ; Marchetti-Deschmann, Martina ; Moszner, Norbert ; Gorsche, Christian
Erschienen in
Macromolecular Chemistry and Physics, 2017, Jg. 218, H. 9
ErschienenWiley, 2017
SpracheEnglisch
DokumenttypAufsatz in einer Zeitschrift
Schlagwörter (EN)chain transfer / hydrosilylation / photopolymerization / thiolene
Projekt-/ReportnummerAustrian Science Fund (FWF): P27059
ISSN1521-3935
URNurn:nbn:at:at-ubtuw:3-5396 Persistent Identifier (URN)
DOI10.1002/macp.201600563 
Zugriffsbeschränkung
 Das Werk ist frei verfügbar
Dateien
Light-triggered radical silane-ene chemistry using a monoalkyl substituted bis(trimethylsilyl)silane [1.4 mb]
Links
Nachweis
Klassifikation
Zusammenfassung (Englisch)

Chain transfer agents (e.g., thiols) enrich radical photopolymerization for use in advanced applications such as stereolithography, optical materials, and biomedicine. Resulting thiolene-based photopolymers exhibit numerous benefits such as tunable thermomechanical properties, and give access to spatially resolved functional materials. Silane-ene chemistry could serve as alternative to this popular thiol-ene approach. A monosubstituted bis(trimethylsilyl)silane (MSiH) is synthesized by a simple one pot procedure. Photoinitiated radical silane-ene chemistry has been performed with multiple enes and the conversions are assessed by 1H NMR spectroscopy. Compared to the most reactive silane from literature, tris(trimethylsilyl)silane (TTMSSiH), the radical reactivity of MSiH is reduced in all tested formulations, but the possibility for further functionalization and accessibility of multifunctional MSiH-derivatives is upheld. A silane-acrylate formulation is found to be most promising. In comparison to a thiolacrylate system, a more uniform conversion of the chain transfer agent and acrylate is shown for the silaneacrylate formulation with MSiH. The promising results for the silane-acrylate system are confirmed by further tests (i.e., NMR spectroscopy, GPC, and MALDI MS), giving additional information on molecular weight regulation and radical mechanism. First MSiH-based photopolymer networks have been fabricated and analyzed via DMTA, thus paving the way for future silane-acrylate networks.

Notiz
Statistik
Das PDF-Dokument wurde 2 mal heruntergeladen.