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A triazine-based Ni(II) PNP pincer complex as catalyst for KumadaCorriu and Negishi cross-coupling reactions
VerfasserMastalir, Mathias ; Kirchner, Karl In der Gemeinsamen Normdatei der DNB nachschlagen
Erschienen in
Monatshefte für Chemie, 2017, Jg. 148, H. 1, S. 105-109
Erschienen2017
Ausgabe
Published version
SpracheEnglisch
DokumenttypAufsatz in einer Zeitschrift
Schlagwörter (EN)Metal complexes / Pincer ligands / Homogeneous catalysis / Cross-coupling / Nickel
URNurn:nbn:at:at-ubtuw:3-2727 Persistent Identifier (URN)
DOI10.1007/s00706-016-1878-4 
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A triazine-based Ni(II) PNP pincer complex as catalyst for KumadaCorriu and Negishi cross-coupling reactions [0.39 mb]
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KumadaCorriu and Negishi cross-coupling reactions, catalyzed efficiently by a Ni(II) PNP pincer complex containing a triazine backbone, are described. The catalyst is able to react with both activated and inactivated aryl halides including chlorides as well as phenol derivatives such as tosylates and mesylates to give the corresponding cross-coupling products in good to excellent isolated yields. A high diversity of substrates was tested under moderate conditions for both types of reactions.

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CC-BY-Lizenz (4.0)Creative Commons Namensnennung 4.0 International Lizenz