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Title
An iron(II) complex featuring 3 and labile 2-bound PNP pincer ligands - striking differences between CH2 and NH spacers
AuthorBichler, Bernhard ; Glatz, Mathias ; Stöger, Berthold ; Mereiter, Kurt In der Gemeinsamen Normdatei der DNB nachschlagen ; Veiros, Luis F. ; Kirchner, Karl In der Gemeinsamen Normdatei der DNB nachschlagen
Published in
Dalton Transactions, London, 2014, Vol. 43, page 14517-14519
PublishedRoyal Society of Chemistry, 2014
Edition
Accepted version
LanguageEnglish
Document typeJournal Article
Project-/ReportnumberP24202-N17
Project-/ReportnumberPEst-OE/QUI/UI0100/2013
ISSN1477-9234
URNurn:nbn:at:at-ubtuw:3-2059 Persistent Identifier (URN)
DOI10.1039/C4DT01933D 
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 The work is publicly available
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An iron(II) complex featuring 3 and labile 2-bound PNP pincer ligands - striking differences between CH2 and NH spacers [0.37 mb]
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Abstract (English)

Treatment of anhydrous FeCl2 with 2 equiv. of the pincer ligand PNP-Ph afforded the diamagnetic cationic octahedral complex [Fe(3-P,N,P-PNP)(2-P,N-PNP)Cl]+ featuring a 2-P,N-bound PNP ligand. Preliminary reactivity studies revealed that the 2-P,N-bound PNP ligand is labile reacting with CO to afford trans-[Fe(PNP-Ph)(CO)2Cl]+.

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