Bibliographic Metadata

Base metal complexes with PCP pincer ligands / von Wolfgang Eder
Additional Titles
Unedle Metall Komplexe mit PCP Pincer Liganden
AuthorEder, Wolfgang
Thesis advisorKirchner, Karl
PublishedWien, 2018
DescriptionIV, 64 Blätter : Illustrationen, Diagramme
Institutional NoteTechnische Universität Wien, Diplomarbeit, 2018
Zusammenfassung in deutscher Sprache
Abweichender Titel nach Übersetzung der Verfasserin/des Verfassers
Document typeThesis (Diplom)
Keywords (DE)Pincer Liganden / Pincerkomplexe / Mangan / Eisen / Kobalt
Keywords (EN)Pincer Ligands / Pincer Complexes / Manganese / Iron / Cobalt
URNurn:nbn:at:at-ubtuw:1-118017 Persistent Identifier (URN)
 The work is publicly available
Base metal complexes with PCP pincer ligands [4.88 mb]
Abstract (English)

In an attempt to facilitate the formation of sigma-C-M bonds, this work describes the synthesis of PCP pincer ligands bearing bromine moieties bonded on the ipso carbon of the benzene backbone. The newly generated ligands were shown to effectively form PCP pincer complexes with a wide variety of base metals. Starting from the metal carbonyl complexes, chromium, molybdenum, tungsten as well as manganese, iron and cobalt PCP complexes were successfully synthesized and fully characterized. Nickel PCP complexes were obtained by directly reacting the metal with the ligand in acetonitrile. All compounds were characterized by means of NMR, HRMS and IR spectroscopy as well as single crystal X-ray diffraction.

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