Bibliographic Metadata

Molecular processes affecting the macroscopic tribological behavior of surfaces / written by Agnieszka Maria Tomala
AuthorTomala, Agnieszka Maria
CensorWerner, Wolfgang
Description213, III S. : Ill., graph. Darst.
Institutional NoteWien, Techn. Univ., Diss., 2011
Document typeDissertation (PhD)
Keywords (DE)Tribology/Lubricants/Additives/Corrosion-inhibitors/ZDDP/Hard Coatings
Keywords (EN)Tribology/Lubricants/Additives/Corrosion-inhibitors/ZDDP/Hard Coatings
Keywords (GND)Oberfläche / Beschichtung / Tribologie / Additiv / Schmierstoff
URNurn:nbn:at:at-ubtuw:1-40610 Persistent Identifier (URN)
 The work is publicly available
Molecular processes affecting the macroscopic tribological behavior of surfaces [18.54 mb]
Abstract (English)

The purpose of this study was to investigate the influence of various additives on the tribological properties of a system in the macro and nanoscale, as well as clarify lubricant interactions with surfaces and materials. To accomplish that a wide range of lubricants and additives were considered. Moreover, a detail chemical analysis was carried out, in order to explain the effect on the friction coefficient, wear mechanisms and corrosion process in lubricated tribosystems.

This research was mainly focused on additives for water based lubricants. Solutions of anti-corrosion and anti-foaming agents - amines, friction modifiers - glycols and amines derivatives with longer hydrocarbon chains were investigated. The results showed that the additives build chemisorbed mono-molecular films on surfaces, what was verified by AFM, AR-XPS and AES analysis, and compared with SESSA simulation. Investigated tribo-films affect the friction coefficient in nanoscale, however during tribological test in the macroscale, they showed different results depending on contact situation (rolling and/or sliding). The conclusion states that the differences in tribological behavior might be due to the orientation of amine and hydroxyl groups on the surfaces. Furthermore, lubricants for rolling bearing elements such as polar and non polar oils with zinc dialkyldithiophosphate (ZDDP) additives were studied. The results demonstrated that a reaction layer formation is strongly dependent on the molecular polarity of the oils and additives.

The evolution of the topography and mechanical properties of the ZDDP-derived tribo-layer with rubbing time showed that initially a thin and soft ZDDP reaction layer develops very quick.

The second part of this work was addressed on chemical vapor deposited (CVD) diamond films and transition metal dichalcogenides (TMD) in consideration of desired properties for micro electro mechanical systems (MEMS). The main scientific goal of this part of the work was to evaluate the influence of surface morphologies on the micro- and nanomechanical properties. Keeping nanotribological application in mind, a comparative AFM analysis were carried out and the influence of carbon content on the mechanical behaviour of such a coatings was evaluated.

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