<div class="csl-bib-body">
<div class="csl-entry">Eder, W. (2018). <i>Base metal complexes with PCP pincer ligands</i> [Diploma Thesis, Technische Universität Wien]. reposiTUm. https://doi.org/10.34726/hss.2018.51044</div>
</div>
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dc.identifier.uri
https://doi.org/10.34726/hss.2018.51044
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/7338
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dc.description
Abweichender Titel nach Übersetzung der Verfasserin/des Verfassers
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dc.description.abstract
In an attempt to facilitate the formation of sigma-C-M bonds, this work describes the synthesis of PCP pincer ligands bearing bromine moieties bonded on the ipso carbon of the benzene backbone. The newly generated ligands were shown to effectively form PCP pincer complexes with a wide variety of base metals. Starting from the metal carbonyl complexes, chromium, molybdenum, tungsten as well as manganese, iron and cobalt PCP complexes were successfully synthesized and fully characterized. Nickel PCP complexes were obtained by directly reacting the metal with the ligand in acetonitrile. All compounds were characterized by means of NMR, HRMS and IR spectroscopy as well as single crystal X-ray diffraction.
en
dc.language
English
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dc.language.iso
en
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dc.rights.uri
http://rightsstatements.org/vocab/InC/1.0/
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dc.subject
Pincer Liganden
de
dc.subject
Pincerkomplexe
de
dc.subject
Mangan
de
dc.subject
Eisen
de
dc.subject
Kobalt
de
dc.subject
Pincer Ligands
en
dc.subject
Pincer Complexes
en
dc.subject
Manganese
en
dc.subject
Iron
en
dc.subject
Cobalt
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dc.title
Base metal complexes with PCP pincer ligands
en
dc.title.alternative
Unedle Metall Komplexe mit PCP Pincer Liganden
de
dc.type
Thesis
en
dc.type
Hochschulschrift
de
dc.rights.license
In Copyright
en
dc.rights.license
Urheberrechtsschutz
de
dc.identifier.doi
10.34726/hss.2018.51044
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dc.contributor.affiliation
TU Wien, Österreich
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dc.rights.holder
Wolfgang Eder
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dc.publisher.place
Wien
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tuw.version
vor
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tuw.thesisinformation
Technische Universität Wien
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dc.contributor.assistant
Mastalir, Matthias
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tuw.publication.orgunit
E163 - Institut für Angewandte Synthesechemie
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dc.type.qualificationlevel
Diploma
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dc.identifier.libraryid
AC15209498
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dc.description.numberOfPages
64
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dc.identifier.urn
urn:nbn:at:at-ubtuw:1-118017
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dc.thesistype
Diplomarbeit
de
dc.thesistype
Diploma Thesis
en
dc.rights.identifier
In Copyright
en
dc.rights.identifier
Urheberrechtsschutz
de
tuw.advisor.staffStatus
staff
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tuw.assistant.staffStatus
staff
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tuw.advisor.orcid
0000-0003-0872-6159
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item.fulltext
with Fulltext
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item.cerifentitytype
Publications
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item.mimetype
application/pdf
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item.openairecristype
http://purl.org/coar/resource_type/c_bdcc
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item.languageiso639-1
en
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item.openaccessfulltext
Open Access
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item.openairetype
master thesis
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item.grantfulltext
open
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crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse