<div class="csl-bib-body">
<div class="csl-entry">Weber, S. (2017). <i>Catalysis with non-precious metals in biphasic systems</i> [Diploma Thesis, Technische Universität Wien]. reposiTUm. https://doi.org/10.34726/hss.2017.48801</div>
</div>
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dc.identifier.uri
https://doi.org/10.34726/hss.2017.48801
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/6313
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dc.description
Abweichender Titel nach Übersetzung der Verfasserin/des Verfassers
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dc.description.abstract
This work is dedicated to the immobilization of a well-defined iron-based catalyst for the reduction of aldehydes to primary alcohols in ionic liquids. The immobilized catalyst was successfully employed in liquid-liquid biphasic catalysis, using the reduction of 4-fluorobenzaldehyde as test reaction. By applying the adjustable nature of ionic liquids and their tunable properties, the reaction parameters could be optimized. The reactivity and the phase behavior of the system could be improved by screening of different ionic liquids. The benefit of liquid-liquid biphasic catalysis was demonstrated in the field of product and catalyst separation. Besides determination of reaction kinetics, recycling of the catalyst was investigated. The potency of this system was finally explored by studying its scope and limitations for a number of aliphatic and aromatic substrates.
en
dc.language
English
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dc.language.iso
en
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dc.rights.uri
http://rightsstatements.org/vocab/InC/1.0/
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dc.subject
Katalyse
de
dc.subject
Ionische Flüssigkeiten
de
dc.subject
Eisen
de
dc.subject
Nachhaltige Chemie
de
dc.subject
Hydrierung
de
dc.subject
Catalysis
en
dc.subject
Ionic Liquids
en
dc.subject
Iron
en
dc.subject
Green chemistry
en
dc.subject
Hydrogenation
en
dc.title
Catalysis with non-precious metals in biphasic systems
en
dc.title.alternative
Zweiphasenkatalyse mit Eisen-basiereneden Katalysatoren
de
dc.type
Thesis
en
dc.type
Hochschulschrift
de
dc.rights.license
In Copyright
en
dc.rights.license
Urheberrechtsschutz
de
dc.identifier.doi
10.34726/hss.2017.48801
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dc.contributor.affiliation
TU Wien, Österreich
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dc.rights.holder
Stefan Weber
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dc.publisher.place
Wien
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tuw.version
vor
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tuw.thesisinformation
Technische Universität Wien
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dc.contributor.assistant
Schröder, Katharina
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tuw.publication.orgunit
E163 - Institut für Angewandte Synthesechemie
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dc.type.qualificationlevel
Diploma
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dc.identifier.libraryid
AC14466219
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dc.description.numberOfPages
84
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dc.identifier.urn
urn:nbn:at:at-ubtuw:1-102248
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dc.thesistype
Diplomarbeit
de
dc.thesistype
Diploma Thesis
en
tuw.author.orcid
0000-0002-1777-0971
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dc.rights.identifier
In Copyright
en
dc.rights.identifier
Urheberrechtsschutz
de
tuw.advisor.staffStatus
staff
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tuw.assistant.staffStatus
staff
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tuw.advisor.orcid
0000-0003-0872-6159
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tuw.assistant.orcid
0000-0002-2515-9873
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item.fulltext
with Fulltext
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item.cerifentitytype
Publications
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item.mimetype
application/pdf
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item.openairecristype
http://purl.org/coar/resource_type/c_bdcc
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item.languageiso639-1
en
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item.openaccessfulltext
Open Access
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item.openairetype
master thesis
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item.grantfulltext
open
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crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse